| Title | Titanium amino alcohol complexes from : α-Titanic acid: X-ray crystal structure of titanium Bis[2,2′-(methylimino)diethanolate] |
| Publication Type | Journal Article |
| Year of Publication | 1999 |
| Authors | Kemmitt, T., Al-Salim N.I., Gainsford G.J., and Henderson W. |
| Journal | Australian Journal of Chemistry |
| Volume | 52 |
| Issue | 10 |
| Pagination | 915 - 919 |
| Date Published | 1999 |
| ISSN | 00049425 (ISSN) |
| Abstract | A method for producing amino alcohol complexes of titanium from hydrated titania (α-titanic acid) is described. Thus hydrated titania was completely converted into triethanolamine and diethanolamine complexes during reaction at 120°C for 6 h. This represents a synthetic method for titanium sol-gel precursors which are free from chlorine-containing impurities. Products were characterized with assistance from 1H and 13C nuclear magnetic resonance spectroscopy, and electrospray mass spectrqmetry. A single-crystal X-ray structure of titanium bis[2,2′-(methylimino)ethanolate], tetragonal, space group P42̄1c, is presented. The titanium centre is coordinated by an N2O4 donor set which can be most closely described as a bifacially capped tetrahedral geometry. |
| URL | http://www.scopus.com/inward/record.url?eid=2-s2.0-0000562150&partnerID=40&md5=a28254cfd7b1fed7bbc7177c12a50de3 |
