Callaghan Innovation Research Papers
| Title | Tert-Butyl (2R,4aR,5aR,11aS,12R,12aR)-8-[bis(tert-butoxycarbonyl)amino]-12- hydroxy-2-methoxy-2,10-dioxo-4,4a,5a,6,9,10,11,11a,12,12a-decahydro-2H-1,3, 5-trioxa-6,7,9,11-tetraaza-2λ5-phosphatetracene-6-carboxylate methanol monosolvate monohydrate |
| Publication Type | Journal Article |
| Year of Publication | 2012 |
| Authors | Gainsford, G.J., Clinch K., Dixon R., and Tiwari A. |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 68 |
| Issue | 7 |
| Pagination | o2250 - o2251 |
| Date Published | 2012 |
| ISSN | 16005368 (ISSN) |
| Abstract | The title compound, C26H40N5O 13P·CH3OH·H2O, crystallizes with one water and one methanol molecule providing important crystal-binding interactions. The compound has the unusual feature of having two butoxy-carbonyl groups bound to one N atom. The conventional attractive hydrogen bonds involving hydroxy, amine and water donors include bifurcations at both donors and acceptors with novel R1 2(6) and R2 1(6) motifs. These are supplemented by C - H⋯O interactions between adjacent molecules forming chain and R2 2(10) ring motifs. © 2012 International Union of Crystallography. |
| URL | http://www.scopus.com/inward/record.url?eid=2-s2.0-84863570813&partnerID=40&md5=7657d3d37fbb32ef3bd54a7de6bff874 |
| DOI | 10.1107/S160053681202867X |