Callaghan Innovation Research Papers

Back to Research Papers

TitleTert-Butyl (2R,4aR,5aR,11aS,12R,12aR)-8-[bis(tert-butoxycarbonyl)amino]-12- hydroxy-2-methoxy-2,10-dioxo-4,4a,5a,6,9,10,11,11a,12,12a-decahydro-2H-1,3, 5-trioxa-6,7,9,11-tetraaza-2λ5-phosphatetracene-6-carboxylate methanol monosolvate monohydrate
Publication TypeJournal Article
Year of Publication2012
AuthorsGainsford, G.J., Clinch K., Dixon R., and Tiwari A.
JournalActa Crystallographica Section E: Structure Reports Online
Paginationo2250 - o2251
Date Published2012
ISSN16005368 (ISSN)
AbstractThe title compound, C26H40N5O 13P·CH3OH·H2O, crystallizes with one water and one methanol molecule providing important crystal-binding interactions. The compound has the unusual feature of having two butoxy-carbonyl groups bound to one N atom. The conventional attractive hydrogen bonds involving hydroxy, amine and water donors include bifurcations at both donors and acceptors with novel R1 2(6) and R2 1(6) motifs. These are supplemented by C - H⋯O interactions between adjacent molecules forming chain and R2 2(10) ring motifs. © 2012 International Union of Crystallography.

Back to top