| Title | Synthesis and optical properties of NLO chromophores containing an indoline donor and azo linker |
| Publication Type | Journal Article |
| Year of Publication | 2012 |
| Authors | Ashraf, M., Teshome A., Kay A.J., Gainsford G.J., Bhuiyan M.D.H., Asselberghs I., and Clays K. |
| Journal | Dyes and Pigments |
| Volume | 95 |
| Issue | 3 |
| Pagination | 455 - 464 |
| Date Published | 2012 |
| ISSN | 01437208 (ISSN) |
| Keywords | Azo dyes, Chromophore synthesis, Chromophores, First hyperpolarizabilities, High yield, Hyper-polarizability, NLO-chromophore, nonlinear optical chromophore, Nonlinear optics, Optical properties, Solvatochromisms, Target compound |
| Abstract | A suite of new nonlinear optical chromophores containing an indoline donor and azo linker has been synthesized in high yields. The methodology used allows for the incorporation of various acceptor systems, the ready isolation of the target compounds and access to materials with excellent thermal stabilities (viz = T d 220-270 °C). The first hyperpolarizabilities of the compounds were measured by hyper-Raleigh scattering and all were found to have an excellent response. The highest value measured was 1640 × 10 -30 esu in DMF at 800 nm for a chromophore containing the well-known TCF acceptor system. Based on data obtained in this and other studies, there is evidence that chromophores containing indoline donors are capable of providing compounds with molecular NLO responses higher than those containing donors derived from N,N-disubstituted anilines. © 2012 Elsevier Ltd. All rights reserved. |
| URL | http://www.scopus.com/inward/record.url?eid=2-s2.0-84864027465&partnerID=40&md5=dae3d40a1990b98a70b8556ba54b6905 |
| DOI | 10.1016/j.dyepig.2012.04.022 |
