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TitleProbing for fluorine in nitrided SiO2 films by ion beam analysis
Publication TypeJournal Article
Year of Publication2001
AuthorsKennedy, V.J., Markwitz A., White G.V., and Brown I.W.M.
JournalModern Physics Letters B
Volume15
Issue28-29
Pagination1332 - 1338
Date Published2001
ISSN02179849 (ISSN)
Keywordsanalytic method, anodic stripping potentiometry, beam therapy, conference paper, film, fluorine, nuclear reactor, phase separation, Sampling, silicon dioxide
AbstractParticle induced γ-ray emission (PIGE) using the 19F(ρ,αγ)16O reaction and deuterium induced nuclear reaction analysis (NRA) were used to measure the uptake of fluorine in thin silicon oxide films which varied in thickness and had been nitrided under various conditions and annealing treatments. PIGE results show that 66 - 80 ppm of F was found in samples nitrided with F (as approximately 1% SiF4) in flowing nitrogen and heated at 1300 °C for 1 hour. With NRA, it was not possible to measure these low concentrations because the background signal from silicon overlaps with the F signal. The increase of F in the nitrided specimens from 66 to 80 ppm follows an increase in film thickness from 3 to 53 nm indicating that F is incorporated in the film rather than being located at the surface of the specimen.
URLhttp://www.scopus.com/inward/record.url?eid=2-s2.0-0035924747&partnerID=40&md5=a96e0b92bfa9dae5eb0e143ae1a4cad7
DOI10.1142/S021798490100324X

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