| Title | A novel titanium-μ-O-zirconium complex: bis(μ-methyliminodiethanolato-1κ3O,N,O′; 1:2κ2O) (methylimino-diethanolato-2κ3 O,N,O′)dipropanolato-1κO,2κO-titanium(IV)-zirconium(IV) |
| Publication Type | Journal Article |
| Year of Publication | 2002 |
| Authors | Gainsford, G.J., Al-Salim N.I., and Kemmitt T. |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 58 |
| Issue | 10 |
| Pagination | m509 - m510 |
| Date Published | 2002 |
| ISSN | 01082701 (ISSN) |
| Keywords | Atoms, carbon, Carbon chains, Conformations, crystal structure, Hydrogen bonds, Isopropanolate ligands, Methylliminodiethanolate ligands, Organometallics, Pentagonal-bipyramidal coordinations, Titanium, X ray analysis, Zirconium |
| Abstract | The title compound, [TiZr(C5H11NO2)3(C3H7O)2], contains three methyliminodiethanolate ligands, two in different μ-oxo bridging coordination modes and one bound only to the Ti atom. The Ti and Zr atoms have distorted octahedral and pentagonal-bipyramidal coordinations, respectively, which share edges. As well as some conformational disorder in the carbon chains, there is chemical disorder at one Ti site, with a mix of n- and isopropanolate ligands. |
| URL | http://www.scopus.com/inward/record.url?eid=2-s2.0-0036805970&partnerID=40&md5=7a5a239821f7fda215844ce6ee4f6d56 |
| DOI | 10.1107/S0108270102015275 |
