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TitleA novel titanium-μ-O-zirconium complex: bis(μ-methyliminodiethanolato-1κ3O,N,O′; 1:2κ2O) (methylimino-diethanolato-2κ3 O,N,O′)dipropanolato-1κO,2κO-titanium(IV)-zirconium(IV)
Publication TypeJournal Article
Year of Publication2002
AuthorsGainsford, G.J., Al-Salim N.I., and Kemmitt T.
JournalActa Crystallographica Section C: Crystal Structure Communications
Paginationm509 - m510
Date Published2002
ISSN01082701 (ISSN)
KeywordsAtoms, carbon, Carbon chains, Conformations, crystal structure, Hydrogen bonds, Isopropanolate ligands, Methylliminodiethanolate ligands, Organometallics, Pentagonal-bipyramidal coordinations, Titanium, X ray analysis, Zirconium
AbstractThe title compound, [TiZr(C5H11NO2)3(C3H7O)2], contains three methyliminodiethanolate ligands, two in different μ-oxo bridging coordination modes and one bound only to the Ti atom. The Ti and Zr atoms have distorted octahedral and pentagonal-bipyramidal coordinations, respectively, which share edges. As well as some conformational disorder in the carbon chains, there is chemical disorder at one Ti site, with a mix of n- and isopropanolate ligands.

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