Callaghan Innovation Research Papers

Back to Research Papers

TitleMultiple bridging modes in a novel trinuclear titanium 1,3-dioxypropane compound, Ti3(methyliminodiethanolate)2(1,3-propanediolate)4
Publication TypeJournal Article
Year of Publication2002
AuthorsKemmitt, T., Gainsford G.J., and Robson-Marsden H.
JournalActa Crystallographica Section C: Crystal Structure Communications
Paginationm310 - m312
Date Published2002
ISSN01082701 (ISSN)
KeywordsBond length, Chemical bonds, Complexation, crystal structure, Organometallics, stereochemistry
AbstractMultiple bridging modes in trinuclear titanium 1,3-dioxypropane compound were studied. The influence of steric factors on the structure of the complex was investigated. Four 1,3-propanediolate ligand were coordinated to the trititanium cluster in three different modes. The Ti-O bond lengths were found in the range, of 1.816 (2) to 2.082 (2)Å, while the average Ti-N distance was 2.391 (3) Å.

Back to top