Title | Multiple bridging modes in a novel trinuclear titanium 1,3-dioxypropane compound, Ti3(methyliminodiethanolate)2(1,3-propanediolate)4 |
Publication Type | Journal Article |
Year of Publication | 2002 |
Authors | Kemmitt, T., Gainsford G.J., and Robson-Marsden H. |
Journal | Acta Crystallographica Section C: Crystal Structure Communications |
Volume | 58 |
Issue | 5 |
Pagination | m310 - m312 |
Date Published | 2002 |
ISSN | 01082701 (ISSN) |
Keywords | Bond length, Chemical bonds, Complexation, crystal structure, Organometallics, stereochemistry |
Abstract | Multiple bridging modes in trinuclear titanium 1,3-dioxypropane compound were studied. The influence of steric factors on the structure of the complex was investigated. Four 1,3-propanediolate ligand were coordinated to the trititanium cluster in three different modes. The Ti-O bond lengths were found in the range, of 1.816 (2) to 2.082 (2)Å, while the average Ti-N distance was 2.391 (3) Å. |
URL | http://www.scopus.com/inward/record.url?eid=2-s2.0-0036587917&partnerID=40&md5=23f5dd3aed6829c8aede278db77dd15b |
DOI | 10.1107/S0108270102006273 |