Title | Inverted spectra of single-wall carbon nanotube films |
Publication Type | Journal Article |
Year of Publication | 2008 |
Authors | Lehman, J.H., Hurst K.E., Roberson L.K., Nield K., and Hamlin J.D. |
Journal | Journal of Physical Chemistry C |
Volume | 112 |
Issue | 31 |
Pagination | 11776 - 11778 |
Date Published | 2008 |
ISSN | 19327447 (ISSN) |
Keywords | Absolute measurements, Absorbance, Absorbance data, Absorbance spectrum, Absorption, Carbon films, Carbon nanotubes, Diffuse reflectance measurements, Excitonic transitions, Fruits, Inverted spectra, Nanocomposites, Nanopores, Nanostructured materials, Nanostructures, Nanotechnology, Nanotubes, Pyro-electric detectors, Pyroelectricity, Reflection, Single wall carbon nano tubes, Single-walled carbon nanotubes (SWCN), Transmissivity, Walls (structural partitions) |
Abstract | We present absolute measurements of reflectance and absorbance for a purified single wall carbon nanotube (SWCNT) film. The absorbance spectrum of a SWCNT-laminated pyroelectric detector for wavelengths 0.6-2 μm is inverted when compared to absorbance data in the literature, which is typically inferred by reciprocity from transmissivity measured by a spectrophotometer. This surprising behavior has been corroborated by diffuse reflectance measurements and suggests that reflectance dominates absorption for wavelengths near excitonic transitions. © 2008 American Chemical Society. |
URL | http://www.scopus.com/inward/record.url?eid=2-s2.0-49649126864&partnerID=40&md5=c5403ef42861dcc702b796b30e35aac9 |
DOI | 10.1021/jp804683z |