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TitleFormation and structural characterisation of an unusual cyclic hexameric oxotitanium complex
Publication TypeJournal Article
Year of Publication1999
AuthorsKemmitt, T., Al-Salim N.I., and Gainsford G.J.
JournalEuropean Journal of Inorganic Chemistry
Pagination1847 - 1849
Date Published1999
ISSN14341948 (ISSN)
Keywordsarticle, complex formation, crystal structure, Hydrolysis, metal complex, synthesis, titanium derivative, X ray diffraction
AbstractTi6O6(MDEA)6·2CH2Cl2 (MDEA - N-methyldiethoxoamine) was obtained by the controlled hydrolysis of the Ti(MDEA)2 complex and analysed by X-ray diffraction. The compound consists of a ring of six [TiO5N] octahedra, edge bridged by μ2-oxide and a μ2-alkoxide arm of the aminoalkoxide ligand.

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