Title | Formation and structural characterisation of an unusual cyclic hexameric oxotitanium complex |
Publication Type | Journal Article |
Year of Publication | 1999 |
Authors | Kemmitt, T., Al-Salim N.I., and Gainsford G.J. |
Journal | European Journal of Inorganic Chemistry |
Issue | 11 |
Pagination | 1847 - 1849 |
Date Published | 1999 |
ISSN | 14341948 (ISSN) |
Keywords | article, complex formation, crystal structure, Hydrolysis, metal complex, synthesis, titanium derivative, X ray diffraction |
Abstract | Ti6O6(MDEA)6·2CH2Cl2 (MDEA - N-methyldiethoxoamine) was obtained by the controlled hydrolysis of the Ti(MDEA)2 complex and analysed by X-ray diffraction. The compound consists of a ring of six [TiO5N] octahedra, edge bridged by μ2-oxide and a μ2-alkoxide arm of the aminoalkoxide ligand. |
URL | http://www.scopus.com/inward/record.url?eid=2-s2.0-0032723450&partnerID=40&md5=8e0de9394b17116bf789a6506482394c |