| Title | The first example of a mixed alkoxide hydride of boron: Sodium boron isopropoxide trihydride |
| Publication Type | Journal Article |
| Year of Publication | 2009 |
| Authors | Gainsford, G.J., Kemmitt T., Jameson G.B., and Telfer S.G. |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 65 |
| Issue | 5 |
| Pagination | m180 - m181 |
| Date Published | 2009 |
| ISSN | 01082701 (ISSN) |
| Keywords | Alkoxide, Boron, Boron compounds, Iso-propoxide, Oxygen, Polymeric layers, Sodium, Sodium compounds, Tetra, Title compounds |
| Abstract | The title compound, poly[[μ-trihydro-(isoprop-oxy)-borato]-sodium(I)], [Na(C3H10BO)] n , forms unique polymeric layers normal to the c axis via Na +⋯O [2.3405 (15) Å] and Na+⋯H(borane) [2.22 (3) and 2.28 (3) Å] inter-actions. This arrangement builds on distorted tetra-hedral Na+, oxygen and boron environments, with one of the borane hydride units uncoordinated, and highlights potential H3B - O-based chemistry. © 2009 International Union of Crystallography. |
| URL | http://www.scopus.com/inward/record.url?eid=2-s2.0-65549144419&partnerID=40&md5=3cc803add107b6933a04a01fb894c722 |
| DOI | 10.1107/S010827010901172X |
