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TitleCost efficient preparation of lead aminoalkoxides directly from lead(II) oxide
Publication TypeJournal Article
Year of Publication2005
AuthorsKemmitt, T., Hubert-Pfalzgraf L.G., Gainsford G.J., and Richard P.
JournalInorganic Chemistry Communications
Pagination1149 - 1153
Date Published2005
ISSN13877003 (ISSN)
AbstractThe preparation of lead(II) aminoalkoxides has been demonstrated from the direct reaction of aminoalcohols with lead(II) oxide. The denticity of the aminoalcohols determined the facility of the reactions, the rate increasing with the number of hydroxyls. Thus, [Pb(dmae)2], 1, [Pb(mdea)]∞, 2, and [Pb(teaH)]2, 3 (dmaeH = dimethylaminoethanol, mdeaH2 = N-methyldiethanolamine, and teaH3 = triethanolamine) have been prepared in high yields and characterized by 1H and 13C NMR. The X-ray crystal structure analyses of 2 and 3 are described. © 2005 Elsevier B.V. All rights reserved.

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