| Title | 2-{3-Cyano-4-[2-(4-diethylamino-2-hy-droxyphenyl)ethenyl]-5,5-dimethyl-2, 5-dihydrofuran-2-ylidene}malononitrile acetone 0.25-solvate |
| Publication Type | Journal Article |
| Year of Publication | 2012 |
| Authors | Gainsford, G.J., Ashraf M., and Kay A.J. |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 68 |
| Issue | 10 |
| Pagination | o2991 - o2992 |
| Date Published | 2012 |
| ISSN | 16005368 (ISSN) |
| Abstract | In the title compound, C22H22N4O 2·0.25C3H6O, the disordered acetone molecule lies with partial occupancy about the 2 axis. The molecule of the malononitrile derivative is essentially planar excluding the methyl groups, with the largest deviation from the mean plane through the non-H atoms being 0.1955 (13) Å. Two rotamers with different orientations of the benzene ring are observed in the ratio of 0.919 (2):0.081 (2), and as a result the OH group is disordered over two sets of sites. In the crystal, the molecules form ribbons along (101) utilizing a strong O - H···N(cyano) hydrogen bond. Interleaving of the nearly planar ribbons is provided by the twofold disordered acetone molecule through C - H···O interactions. |
| URL | http://www.scopus.com/inward/record.url?eid=2-s2.0-84867222006&partnerID=40&md5=e271c139dae6bf0e09438eb8ae3f20e8 |
| DOI | 10.1107/S1600536812039736 |
